2007-2017年中国沙尘气溶胶的三维分布特征及输送过程

利用最新发布的CALIPSO产品，构建了2007-2017年中国沙尘气溶胶的三维分布，并结合HYSPLIT-4模式和再分析数据，探讨了沙尘的三维输送过程。结果表明：中国的沙尘排放源区主要是塔克拉玛干沙漠和巴丹吉林沙漠，沙尘气溶胶出现频率分别为60%和35%。塔克拉玛干沙漠排放的沙尘主要（50%~70%）停留在源地0~6 000 m高度，少部分向东输送至甘肃和内蒙古；巴丹吉林沙漠排放的沙尘则主要向东输送。中国沙尘排放量在春季最大，向东输送最强；夏季，东亚夏季风限制了沙尘向东输送；秋季，沙尘排放减弱，输送强度和夏季相当；沙尘排放量在冬季最小，输送最弱。夏季，沙尘在输送过程中可被抬升至高度5 000 m以上，春季次之，秋、冬季的沙尘主要在低层大气输送。沙尘在向东输送的过程中被抬升并和当地人为污染物混合变为污染性沙尘，华北地区污染性沙尘出现频率高达30%；输送到海洋的沙尘也会与洋面上（0~3 000 m高度）的海盐气溶胶混合，出现频率约为10%。     

长江河口潮波传播机制及阈值效应分析

河口潮波传播过程受沿程地形(如河宽辐聚、水深变化)及上游径流等诸多因素影响,时空变化复杂。径潮动力非线性相互作用研究有利于揭示河口潮波传播的动力学机制,对河口区水资源高效开发利用具有重要指导意义。本文基于2007—2009年长江河口沿程天生港、江阴、镇江、南京、马鞍山、芜湖的逐日高、低潮位数据及大通站日均流量数据,统计分析不同河段潮波衰减率与余水位坡度随流量的变化特征,结果表明潮波衰减率绝对值与余水位坡度随流量增大并不是单调递增,而是存在一个阈值流量和区域,对应潮波衰减效应的极大值。为揭示这一阈值现象,采用一维水动力解析模型对研究河段的潮波传播过程进行模拟。结果表明,潮波传播的阈值现象主要是由于洪季上游回水作用随流量加强,余水位及水深增大,导致河口辐聚程度减小,而余水位坡度为适应河口形状变化亦有所减小,从而形成相对应的阈值流量和区域。     

烃源岩不同性质有机酸的分离及其检测方法

烃源岩中的有机酸来源于有机质，但有机质具有不同的赋存形式，有机酸具有不同性质，这将影响有机酸与不同赋存有机质的关系，进而影响分离和检测方法。文章在总结前人对有机质赋存形式和有机酸性质等特征的基础上，提出烃源岩中的有机酸并以非单一的形式存在，具有水溶性、脂溶性和难溶性有机酸三种类型，游离有机质中存在水溶性和脂溶性有机酸，而结合有机质中存在水溶性、脂溶性和难溶性有机酸。因此在检测方法上需采取分步分离的方法，且根据有机酸的性质选取合适的检测方法，即水溶性有机酸利用离子色谱检测，索氏抽提得到的脂溶性有机酸利用气相色谱—质谱检测，通过酸解抽提残渣得到的难溶性有机酸利用红外光谱检测，全面系统地认识烃源岩中有机酸含量和类型等特征。这对进一步探讨烃源岩各种类型有机酸特征和演化规律，深化烃源岩有机质生烃以及有机—无机相互作用等机理都具有重要意义。     

中国台商农业技术时空扩散的格局、路径与机制——以福建省漳浦县为例

结合统计数据及实地调研、访谈数据,研究中国台湾青枣种植技术透过台商直接投资渠道在福建省漳浦县落地、发散与传播过程,分析其时空扩散路径、格局与机制,以期揭示中国台商农业技术在中国大陆地区独具特色的扩散规律与机制,为加速两岸农业合作交流、制定技术应用政策提供理论与实践依据。研究发现,在时间维度,中国台商农业技术扩散过程呈现典型的S型曲线,但其扩散迅速、周期较短,扩散阻力小且示范效应显著;在空间维度,形成多核心、多强度、梯度扩散体系（中国台湾扩散源与本地扩散节点）,扩散场相互叠加,以就近扩展扩散为主、等级扩散为辅的特色扩散格局。     

不同顶管组合方式的管幕冻结温度场模型试验

拱北隧道作为港珠澳大桥珠海连接线的关键性工程， 在国内外首次成功运用了管幕冻结技术。以此为背景， 为更加全面地掌握饱和软土地层中管幕冻结温度场的分布特点， 开展了不同顶管组合方式下的管幕冻结温度场模型试验研究。试验结果表明： 各测点温度曲线在积极冻结期前4 h急剧下降， 随后逐渐减缓， 降至砂土冰点后趋于平稳， 三种布管方式均满足冻结设计要求； 冻结管中低温盐水提供的冷量首先传递给顶管管壁， 再以“面”的形式均匀地传递给周围土体； 积极冻结21 h后， 采用四根空顶管组合的C区冻结壁竖向范围最大， 空管管壁正上方冻结壁平均厚度约为105 mm， 在满足管幕刚度设计要求的前提下， 可采此布管方式以达到快速形成冻结帷幕的目的。限位管开启后的4 h内， 实顶管中线垂直距离100 mm范围内测点温度曲线虽有明显回升但仍维持在冻土冰点以下， 超出此范围后温度变化影响逐渐减弱， 且顶管间冻结壁稳定存在， 表明限位管在满足管间有效封水的条件下， 能在一定范围内起到定向限制地层冻胀的作用。优化后的双圆形冻结管在满足冻结设计要求的同时， 更加便于安装且经济环保。     

全二维气相色谱-电子捕获检测器测定复杂基质土壤中24种有机氯和拟除虫菊酯类农药

目前针对环境样品中有机氯和拟除虫菊酯类农药的检测方法主要有气相色谱法和气相色谱-质谱法（GC-MS），由于气相色谱法采用电子捕获检测器从而具有较高的灵敏度，在污染物的环境行为研究中得到广泛应用，GC-MS法的定性效果好，但检测灵敏度相对偏低。本文研究了2018年土壤详查江苏地区样品中有机氯农药和拟除虫菊酯的残留状况，结果显示，即使经过多次净化仍有20%的样品存在假阳性或基质干扰现象。为了提高定性准确度，同时保证检测灵敏度，实验建立了复杂基质土壤中20种有机氯农药和4种拟除虫菊酯的全二维气相色谱-电子捕获检测器检测方法，最终选择中等极性的TG-35MS为第一色谱柱，非极性的（DB-1）为第二色谱柱，将鲜样与无水硫酸钠混合均匀后，以正己烷-丙酮（1：1，V/V）为提取剂进行索氏提取，采用全二维气相色谱-电子捕获检测器进行检测，外标法定量。各物质的质量浓度均在1.0~500μg/L内与其峰面积呈线性关系，相关系数均大于0.995，检出限为0.02~0.17μg/kg。用标准加入法进行回收实验，测得回收率为80.7%~103.5%，测定值的相对标准偏差（n=6）为1.84%~10.12%。本方法将高灵敏度检测器与全二维色谱相结合，在保证检测灵敏度的同时增加了峰容量，有效去除了基质干扰。相比2018年土壤详查参考方法HJ 835—2017的检出限0.02~0.09mg/kg（全扫模式），本方法检出限显著降低，且操作简单，可为复杂基质样品中的痕量超痕量检测提供参考。     

水资源约束下的河西走廊城市经济脆弱性时空演变及其影响因素

城市经济脆弱性作为当前脆弱性研究中的重要领域，为人-地系统耦合研究提供了新的视角，并为城市可持续健康发展提供有益的决策支持和管理方法。依据城市经济脆弱性内涵，基于暴露度、敏感性、适应能力构建了城市经济脆弱性评价指标体系，运用熵权TOPSIS法评价河西走廊地区及区域内五市的城市经济脆弱性，并采用障碍度模型识别影响区域城市经济脆弱性变化的因素。结果显示：（1）2006—2015年，河西走廊地区城市经济脆弱性呈现出先曲折下降（2006—2011年）再波动上升趋势（2012—2015年）；（2）河西走廊地区的城市经济脆弱性具有明显的空间特征，经历了东西高、中部低到整体较高的演变过程；（3）阻碍河西走廊地区城市经济脆弱性降低的障碍因子由适应能力逐步转变为暴露度。针对河西走廊地区各市主要障碍因子，提出针对性优化措施。     

Morphodynamics of an Artificial Cobble Beach in Tianquan Bay,Xiamen, China

By tracking and monitoring the profile configuration, topography, and hydrodynamic factors of an artificial cobble beach in Tianquan Bay, Xiamen, China over three consecutive years after its completion, we analyzed the evolution of its profile configuration and plane morphology, and its storm response characteristics. The evolution of the profile configuration of the artificial cobble beach in Tianquan Bay can be divided into four stages. The beach was unstable during the initial stage after the beach nourishment the profile configuration changed obviously, and an upper concave composite cobble beach formed gradually, which was characterized by a steep upper part and a gentle lower part. In the second stage, the cobble beach approached dynamic equilibrium with minor changes in the profile configuration. At the third stage the beach was in a high-energy state under the influence of Typhoon Meranti, and the response of the artificial cobble beach differed significantly from that of the low-tide terrace sandy beach. Within a short time, there was net onshore transport of cobbles in the cross-shore direction. The beach face was eroded, the beach berm was accumulated, and the slope of the beach was steepened considerably. In the alongshore direction, there was notable transport of cobbles on the beach from east to west along the shore, and the total volume of the beach decreased by 4.5×103 m~3, which accounted for 50% of the total amount of beach volume lost within three years. The fourth stage was the restoration stage after the typhoon, characterized by a little gentler profile slope and the increase in width and the decrease in height of beach berm. Because of the action of waves and the wave-driven longshore current caused by the specific terrain and landform conditions along the coast(e.g., coastal headlands, near-shore artificial structures, and reefs), the coastline of the artificial cobble beach gradually evolved from being essentially parallel to the artificial coast upon completion to a slightly curved parabolic shape, and three distinct erosion hotspots were formed on the west side of the cape and the artificial drainpipe, and the reefs. Generally, the adoption of cobbles for beach nourishment on this macro-tidal coast beach with severe erosion has yielded excellent stability and adaptability.     

Hydrological management strategies for the control of algal blooms in regulated lowland rivers

Reservoirs of lowland floodplain rivers with eutrophic backgrounds cause variations in the hydrological and hydraulic conditions of estuaries and low-dam reservoir areas, which can promote planktonic algae to proliferate and algal bloom outbreaks. Understanding the ecological effects of variations in hydrological and hydraulic processes in lowland rivers is important for algal bloom control. In this study, the middle and lower reaches of the Han River, China, a typical regulated lowland river with a eutrophic background, are selected. Based on the effect of hydrological and hydraulic variability on algal blooms, a hydrological management strategy for river algal bloom control is proposed. The results showed that (a) differences in river morphology and background nutrient levels cause significant differences in the critical threshold flow velocities for algal bloom outbreaks between natural river and low-dam reservoir sections; there is no uniform threshold flow velocity for algal bloom control. (b) There are significant differences in the river hydrological/hydraulic conditions between years with and without algal blooms. The average river flow, water level and velocity in years with algal blooms are significantly lower than those in years without algal blooms. (c) For different river sections where algal blooms occur and to meet the threshold flow velocities, the joint operation of cascade reservoirs and diversion projects is an effective method to prevent and control algal blooms in regulated lowland rivers. This study is expected to deepen our understanding of the ecological significance of special hydrological processes and guide algal bloom management in regulated lowland rivers.     

Changes of Biogenic Elements in Phragmites australis and Suaeda salsa from Salt Marshes in Yellow River Delta,China

Little information is available on biogenic elements(carbon, nitrogen, phosphorus and sulfur) and the ecological stoichiometric characteristics of plants in coastal wetlands. To investigate the contents of carbon, nitrogen, phosphorus and sulfur of plants, and their ecological stoichiometric characteristics in the Yellow(Huanghe) River Delta, plant samples were collected from two typical salt marshes(Suaeda salsa and Phragmites australis wetlands) during the period of from August to October in 2007, and the ratios of C/N, C/P, N/P, C/N/P and C/N/P/S were calculated. Results showed that during the studying period, plant C, N and P were lower than the global average values, and plant N and P were lower than the China's average values. Leaf C and S in Suaeda salsa were significantly lower than those in Phragmites australis(P 0.05), and leaf N and P in Suaeda salsa and Phragmites australis showed no significant differences(P 0.05). Average C/N ratios were 23.75 in leaf, 73.36 in stem, 65.67 in root of Suaeda salsa, and 33.77 in leaf, 121.68 in stem, 97.13 in root of Phragmites australis. Average C/N ratios of Suaeda salsa and Phragmites australis were all great than 25, indicating the salt marsh in the Yellow River Delta is an N limitation system. Average C/P ratios were 276.78 in leaf, 709.28 in stem and 1031.32 in root of Suaeda salsa, and 536.94 in leaf, 768.13 in stem and 875.22 in root of Phragmites australis. The average N/P ratios of Suaeda salsa were 12.92 in leaf, 10.77 in stem and 10.91 in root, and the average N/P ratios of Phragmites australis were 16.40 in leaf, 7.40 in stem and 6.92 in root, indicating the Suaeda salsa wetlands were N limited and Phragmites australis wetlands were N limited in August and P limited in October in 2007. The average C/N, C/P and C/N/P ratios in Suaeda salsa and Pragmites australis were higher than the global average values, indicating the lower quality of organic matter provided by wetland plants in the Yellow River delta.